{N-[(2-Oxido-1-naphthyl)methylidene]serinato-κ3 O,N,O′}(1,10-phenanthroline-κ2 N,N′)copper(II)
نویسندگان
چکیده
In the title complex, [Cu(C(14)H(11)NO(4))(C(12)H(8)N(2))], the tridentate Schiff base ligand is derived from the condensation of 2-hydr-oxy-1-naphthaldehyde and l-serine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter-molecular O-H⋯O and C-H⋯O hydrogen bonds results in a two-dimensional network structure parallel to (001).
منابع مشابه
Oxido{N-[(2-oxido-1-naphthyl-κO)methylidene]asparaginato-κ2 O 1,N 2}(1,10-phenanthroline-κ2 N,N′)vanadium(IV) N,N-dimethylformamide monosolvate
The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy-droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa-hedral geometry. In the cry...
متن کاملDi-μ-benzoato-κ3 O,O′:O;κ3 O:O,O′-bis[(benzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)lead(II)]
In the centrosymmetric dinuclear title compound, [Pb(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], two Pb(2+) ions are connected by two tridentate bridging benzoate anions. The Pb(2+) ion is seven-coordinated by five O atoms from three benzoate anions and two N atoms from the 1,10-phenanthroline ligands. The benzoate anions adopt two different coordination modes, one bidentate-chelating and one tride...
متن کاملDi-μ-acetato-κ3 O,O′:O;κ3 O:O,O′-bis[(acetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium(II)]
The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π-π inter-action between...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)lead(II)]-di-μ-nitrato-κ3 O,O′:O′′;κ3 O:O′,O′′-[(1,10-phenanthroline-κ2 N,N′)lead(II)]-bis(μ-2,2,2-trichloroacetato-κ2 O:O′)]
In the title Pb(II) complex, [Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)](n), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloro-acetate anion is bidentate, bridging two Pb(II) ions. The coordination geometry is based on a penta-gonal-bipramidal geometry defi...
متن کاملAqua(2-oxido-2,2-diphenylacetato-κ2 O 1,O 2)(1,10-phenanthroline-κ2 N,N′)copper(II)
In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water mol-ecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via inter-molecular O-H⋯O and C-H⋯O hydrogen bonds, C-H⋯π inter-actions an...
متن کامل